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Surface-directed spinodal decomposition on chemically patterned substrates
P. Das, , S. Puri
Published in American Physical Society
2020
PMID: 32794988
Volume: 102
   
Issue: 1
Abstract
Surface-directed spinodal decomposition (SDSD) is the kinetic interplay of phase separation and wetting at a surface. This process is of great scientific and technological importance. In this paper, we report results from a numerical study of SDSD on a chemically patterned substrate. We consider simple surface patterns for our simulations, but most of the results apply for arbitrary patterns. In layers near the surface, we observe a dynamical crossover from a surface-registry regime to a phase-separation regime. We study this crossover using layerwise correlation functions and structure factors and domain length scales. © 2020 American Physical Society.
Figures & Tables (11)
  • Figure-0
    FIG. 1. Schematic of a chemically patterned substrate. ... Expand
  • Figure-1
    FIG. 2. Snapshots of SDSD in an unstable binary (AB) mixture ... Expand
  • Figure-2
    FIG. 4. Snapshots of SDSD in an unstable binary (AB) mixture ... Expand
  • Figure-3
    FIG. 3. Order-parameter profiles ... Expand
  • Figure-4
    FIG. 5. Snapshots at t = 5400 ... Expand
  • Figure-5
    FIG. 6. Snapshots at t = 5400 and z = 5 for patch sizes ... Expand
  • Figure-6
    FIG. 8. Time-dependence of the characteristic length scale L(z, ... Expand
  • Figure-7
    FIG. 7. Scaling plot of layerwise correlation functions ... Expand
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About the journal
JournalData powered by SciSpacePhysical Review E
PublisherData powered by SciSpaceAmerican Physical Society
ISSN24700045