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Substrate induced tuning of compressive strain and phonon modes in large area MoS2 and WS2 van der Waals epitaxial thin films
R Sahu, D Radhakrishnan, B Vishal, , A Sil, C Narayana, R Datta
Published in Elsevier B.V.
2017
Volume: 470
   
Pages: 51 - 57
Abstract
Large area MoS2 and WS2 van der Waals epitaxial thin films with control over number of layers including monolayer is grown by pulsed laser deposition utilizing slower growth kinetics. The films grown on c-plane sapphire show stiffening of A1g and E12g phonon modes with decreasing number of layers for both MoS2 and WS2. The observed stiffening translate into the compressive strain of 0.52% & 0.53% with accompanying increase in fundamental direct band gap to 1.74 and 1.68 eV for monolayer MoS2 and WS2, respectively. The strain decays with the number of layers. HRTEM imaging directly reveals the nature of atomic registry of van der Waals layers with the substrate and the associated compressive strain. The results demonstrate a practical route to stabilize and engineer strain for this class of material over large area device fabrication. © 2017 Elsevier B.V.
About the journal
JournalData powered by TypesetJournal of Crystal Growth
PublisherData powered by TypesetElsevier B.V.
ISSN00220248
Open AccessNo