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Phenyl hydrazine as initiator for direct arene C-H arylation via base promoted homolytic aromatic substitutionPublished in
2013
DOI: 10.1021/ol402995e
PMID: 24251964
Volume: 15
Issue: 23
Pages: 6102 - 6105
A simple and efficient direct radical arylation of unactivated arenes is described which uses cheap and commercially available phenyl hydrazine as an initiator. The reaction occurs through a base promoted homolytic aromatic substitution (BHAS) mechanism involving aryl radicals and aryl radical anions as intermediates and offers a practical approach for preparation of an array of substituted biaryls. © 2013 American Chemical Society.
Preprint Version
Content may be subject to copyright.This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in Org... ...This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in Organic Letters, copyright © American Chemical Society after peer review. To access the final edited and published work see https://doi.org/10.1021/ol402995e
About the journal
| Journal | Organic Letters |
|---|---|
| ISSN | 15237060 |
Authors (1)
Sandip Murarka- Department of Chemistry IIT Jodhpur
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