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Ni/graphitic carbon core-shell nanostructure-based light weight elastomeric composites for Ku-band microwave absorption applications
L. Saini, M.K. Patra, M.K. Dhaka, R.K. Jani, G.K. Gupta, ,
Published in Royal Society of Chemistry
2018
Volume: 20
   
Issue: 32
Pages: 4630 - 4640
Abstract
Graphitic carbon-coated Ni metal core nanoparticles are synthesized using controlled thermal treatment of Ni-hydroxide in an aniline-formaldehyde copolymer matrix under a N2 atmosphere. The structural and microstructural studies substantiate the formation of a graphitic shell on the metallic nickel core. The 850 °C heat-treated core-shell structured material is ferromagnetic in nature with high saturation magnetization. The sample with the highest value of magnetic moment is impregnated in a rubber matrix to prepare composite samples with core-shell nanomaterials of different weight fractions. The sample with 70 wt% Ni/graphitic carbon core-shell powder in the elastomeric rubber matrix showed the optimal microwave absorption at a fairly low thickness of ∼1 mm. This is attributed to the optimized combination of the effective impedance matching and interfacial polarization losses. Further increase in the Ni/graphitic carbon filler material resulted in reduced microwave absorption due to the greater mismatch of impedance as compared to the desired free space impedance of ∼377 Ω. Thus, the optimized composite material is of great potential for microwave absorption in the Ku band. © 2018 The Royal Society of Chemistry.
About the journal
JournalData powered by TypesetCrystEngComm
PublisherData powered by TypesetRoyal Society of Chemistry
ISSN14668033