Graphene was synthesized and used as a counter electrode in place of platinum in dye sensitized solar cells. This study reveals that the graphene synthesized by reduction of graphene oxide still contains functional groups even after reduction. The synthesized graphene counter electrodes were prepared by screen printing fabrication techniques. The influence of temperature variation on the films morphology, crystallinity, and its interfacial adhesiveness to the fluorine doped tin oxide coated glass were studied. Screen printing technique has shown uniform surface, decreased agglomeration of nanoparticles and high film adhesiveness. The screen printed film annealed at 400 degrees C reveals best surface morphology