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Covalent functionalization of molybdenum disulfide by chemically activated diazonium salts
, J Teyssandier, S Eyley, S Kazzi El, M Gonzalez C R, B Pradhan, ...
Published in Royal Society of Chemistry
2021
PMID: 33508050
Volume: 13
   
Issue: 5
Pages: 2972 - 2981
Abstract
Covalent functionalization is one of the most efficient ways to tune the properties of layered materials in a highly controlled manner. However, molecular chemisorption on semiconducting transition metal dichalcogenides remains a delicate task due to the inertness of their surface. Here we perform covalent modification of bulk and single layer molybdenum disulfide (MoS2) using chemical activation of diazonium salts. A high level of control over the grafting density and yield on MoS2 basal plane can be achieved by this approach. Using scanning probe microscopies and X-ray photoelectron spectroscopy we prove the covalent functionalization of MoS2. This journal is © The Royal Society of Chemistry.
About the journal
JournalData powered by TypesetNanoscale
PublisherData powered by TypesetRoyal Society of Chemistry
ISSN20403364
Open AccessNo