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Coordination of N,O-donor appended Schiff base ligand (H2L1) towards Zinc(II) in presence of pseudohalides: Syntheses, crystal structures, photoluminescence, antimicrobial activities and Hirshfeld surfacesPublished in Elsevier B.V.
2018
Volume: 1155
Pages: 745 - 757
A series of dinuclear Zn(II) complexes [Zn2 (L1) (CH3OH)2(SCN) (OAc)](1), [Zn2 (L1) (CH3OH)2(N3)2](2) and [Zn2 (L1) (Cl)2(CH3OH)]·CH3OH (3) have been synthesized by the reaction of compartmental Schiff base ligand (H2L1) [N,N′-Bis(3-ethoxysalicylidenimino)-1,3-diaminopropane] with Zn(OAc)2·2H2O in presence of coligand like KSCN, NaN3 and NaCl respectively. X-ray diffraction analysis revealed that all the complexes are neutral and possess a 4-membered Zn2 (μ2-O)2 ring fastened by the unified coordination action of a doubly deprotonated ligand. In addition, solid state structure of the complexes display extensive intermolecular interaction which has been supported theoretically by Hirshfeld surface analysis with 2D Fingerprint plots. The synthesized Zn(II) metal complexes observed enhancement of luminescence emission compared to the parent Schiff base due to emanating ligand based intraligand (π→π∗) fluorescence. Additionally, Zn(II) metal complexes exhibited considerable antimicrobial potency against some important Gram +ve and Gram -ve bacteria. © 2017 Elsevier B.V.
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About the journal
| Journal | Data powered by TypesetJournal of Molecular Structure |
|---|---|
| Publisher | Data powered by TypesetElsevier B.V. |
| ISSN | 00222860 |
| Open Access | No |
Authors (2)
Ramesh K. Metre- Department of Chemistry IIT Jodhpur
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- Pd-Catalyzed Four-Component Sequential Reaction Delivers a Modular Fluorophore Platform for Cell Imaging
- Cd(II) Pseudohalide Complexes with N, N′-Bis(3-ethoxysalicylidenimino) 1,3-Diaminopropane: Crystal Structures, Hirshfeld Surface, Antibacterial and Anti-Biofilm Properties
- Octanuclear Organotin Copper Sulfide Cage [(RSnCu)4(μ3-S)8]·2CHCl3 (R = 2-phenylazophenyl) Assembled using Intramolecular Coordination Approach: Synthesis, Structure and DFT-NBO-AIM Analysis
Deepak Mishra- Department of Computer Science & Engineering IIT Jodhpur
- Cd(II) Pseudohalide Complexes with N, N′-Bis(3-ethoxysalicylidenimino) 1,3-Diaminopropane: Crystal Structures, Hirshfeld Surface, Antibacterial and Anti-Biofilm Properties
- Nitrato, Pseudohalo-Linked Zn(II)/Cd(II) Schiff-Base Complexes with 1,3-Diimine Spacer Group: Syntheses, Crystal Structures, DFT, TD-DFT and Fluorescence Studies
- Coordination of N,O-donor appended Schiff base ligand (H2L1) towards Zinc(II) in presence of pseudohalides: Syntheses, crystal structures, photoluminescence, antimicrobial activities and Hirshfeld surfaces
- A Power Efficient Image Sensor Readout with On-Chip δ -Interpolation Using Reconfigurable ADC
