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Biomimetic total syntheses of flinderoles B and C
D.H. Dethe, , A. Ranjan
Published in
PMID: 21314186
Volume: 133
Issue: 9
Pages: 2864 - 2867
A simple and efficient biomimetic synthesis of pyrrolo[1,2-a]indoles using a highly stereo- and regioselective [3 + 2] reaction cascade was developed and then further applied in the first total synthesis of flinderoles B and C, which proceeded in 17.2% yield over the longest linear sequence of 11 steps. © 2011 American Chemical Society.
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JournalJournal of the American Chemical Society