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Biology-Oriented Synthesis of Decahydro-4,8-epoxyazulene Scaffolds
Z.-J. Jia, C. Merten, L. Knauer, , C. Strohmann, H. Waldmann
Published in Georg Thieme Verlag
2017
Volume: 28
   
Issue: 20
Pages: 2918 - 2922
Abstract
Guided by the principle of biology-oriented synthesis, a collection of compounds with decahydro-4,8-epoxyazulene scaffold occurring in bioactive natural products was synthesized by the rhodium(II)-catalyzed 1,3-dipolar cycloaddition reaction of pentafulvenes and carbonyl ylides. The products can be obtained in moderate to high yields, with moderate enantioselectivity and excellent diastereoselectivity and regioselectivity. © Georg Thieme Verlag Stuttgart. New York.
About the journal
JournalSynlett
PublisherGeorg Thieme Verlag
ISSN09365214
Open AccessNo