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A Sustainable Palladium-Intercalated Montmorillonite Clay Catalytic System for Imine Hydrogenation under Mild Conditions
Unnati Gupta, R. Krishnapriya,
Published in WILEY-V C H VERLAG GMBH
2021
PMID: 33369219
Volume: 86
   
Issue: 4
Pages: 540 - 548
Abstract
A series of palladium nanoparticles (Pd NPs) intercalated montmorillonite clay catalysts is reported for hydrogenation of 3-diphenyl prop-2-en-1-imine under mild reaction conditions. Pd/clay catalyst was prepared by a simple wet-impregnation method, and the physicochemical properties were characterized extensively by various techniques including N-2 adsorption, XRD, TEM, XPS and TPR etc., which showed the intercalation of active Pd NPs between the clay layers. The effect of reaction conditions such as catalyst loading, reaction time, temperature and H-2 pressure is explored, and thereby a plausible mechanism is proposed. The optimum amount of 6 wt \% Pd/clay catalyst showed significant catalytic activity to yield 3-phenyl propyl aniline with 100 \% conversion and selectivity under 5 bar pressure and a shorter reaction period of 3.5 h at 100 degrees C. The developed catalytic system unveiled excellent reusability over five cycles and hence paved the way for industrial applications.
About the journal
JournalData powered by TypesetCHEMPLUSCHEM
PublisherData powered by TypesetWILEY-V C H VERLAG GMBH
ISSN2192-6506
Open AccessNo